Articles

GOLD NANOPARTICLES AND SENSOR TECHNOLOGY FOR SENSITIVE ETHYLENE DETECTION

Article number
934_31
Pages
255 – 262
Language
English
Abstract
A new electrocatalytic sensor for continuous in-situ measurement of gaseous ethylene (C2H4) in air is presented.
The measuring principle is based on ethylene oxidation on a gold-Nafion anode with weak sulphuric acid used as the electrolyte.
The small ethylene molecules are trapped in the pores of the nanoporous gold matrix and partly consumed to produce the signal proportional to their concentration in air.
The high surface area of the nanoporous gold catalyst renders high sensitivity and fast response in detection of ethylene in air making it particularly suitable for postharvest or plant physiology applications.
In the current study, the accuracy was 96-98% with a standard deviation (SD) of 0.05-0.15 µl L-1 C2H4 and a variation coefficient of 0.5-2%, when the calibration gas of 8 µl L-1 C2H4 was measured after calibration.
The measuring range of the device is 0-50 µl L-1 C2H4 with an accuracy of ±5% of reading and displayed resolution of 1 nl L-1. For a 30-s measurement, the instrument draws a ca. 150 ml gas sample and appears suitable for measurement of individual fruit in an open or closed gas system, for continuous sampling or single gas samples.
Tempera-ture, humidity, CO2 (optional sensor) and another gas or ethylene analogue like MCP (optional sensor) are displayed concomitantly.
The reproducibility of the C2H4 values was 93% with 3 subsequent measurements of a variety of fruits.
The unit can be operated on mains or built-in battery providing up to 8 hours operation and weighs 4.5 kg.
This makes it portable for in situ ethylene measurement after calibration with an external gas supply and is a better alternative to measurement of ethylene in the head space of a respiration chamber.

Publication
Authors
M.M. Blanke, R. Shekarriz
Keywords
ethylene, degreening, ethylene scrubber, flower induction, nanotechnology, fruit, 1-MCP, sensor technology, food supply chain
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